规整有机分子自聚集体对铜的高效缓蚀的研究

通过多步法合成了离子型含双苯并三氮唑环的目标分子，4，4'-{苯-1，3-二基二[(1E)-3-羰基丙-1-烯-1，3-二基]}二[2-(2H-苯并三唑-2-基)苯醇酸]二钾。在室温条件下，目标分子在3.5%（质量）NaCl/DMSO（二甲基亚枫）混合溶液 （体积比：40/60） 中能够发生分子自组装产生纳-微米级的自聚集体。通过傅里叶变换红外光谱 （FT-IR）、拉曼光谱和X射线光电子能谱 （XPS） 的表征，证实了所形成的目标分子自聚集体能够对铜表面产生强烈的化学吸附作用，在铜表面形成自组装膜。利用电化学方法测定了目标分子自聚集体吸附在铜表面形成自组装膜后，在3.5%（质量）NaCl溶液中的缓蚀性能。结果表明目标分子自聚集体在NaCl溶液中能高效地抑制铜腐蚀。     

Improved Input and State Estimation for Linear Stochastic Systems with Direct Feedthrough

This paper is concerned with the problem of joint input and state estimation for linear stochastic systems with direct feedthrough. Based on the fact that each unknown input between any two time steps is always bounded, a novel improved algorithm is proposed. Compared with existing results, this algorithm can effectively enhance estimation accuracy. Moreover, the stability of the algorithm is also discussed. Finally, an illustrative example is given to demonstrate the effectiveness of the proposed approach.     

基于状态空间法的电动机故障诊断和识别

电动机的初期故障信号一般较弱,不易辨别,而状态空间法在小信号的处理中灵敏度很高。为达到对电动机故障的诊断和识别,试图把状态空间法应用到对电动机的故障诊断中,先通过推导,从数学理论层面分析了状态空间法对于电动机故障信号的可辨别性,再使用Matlab软件搭建状态空间的辨别模型,把实验台测试的三组数据导入到模型中进行测试。测试的结果有力地证明了此方法的可行性,并能克服快速傅里叶变换(FFT)中数据采集量较大、分辨率不高的缺点。     

Modelling of electron energy absorption and backscattering during EBW

A three-dimensional heat flux model for deep-penetrating electron beam welding (EBW) is established to mathematically describe the physical heat generation process during interaction between electrons and the dynamic molten pool free surface. Monte Carlo method is used to determine the electron-target interaction, and random distribution of initial electrons, progressive trajectory tracing and electron backscattering models are used to describe the spatial distribution of electrons absorption. The model is verified in preset keyholes and applied in the simulation on electron beam welding process, and the calculated bead shape shows a good consistency with experimental results.     

Recent progress of green sorbents-based technologies for low concentration CO2 capture

The increased concentration of CO₂ due to continuous breathing and no discharge of human beings in the manned closed space, like spacecraft and submarines, can be a threat to health and safety. Effective removal of low concentration CO₂ from the manned closed space is essential to meet the requirements of long-term space or deep-sea exploration, which is an international frontier and trend. Ionic liquids (ILs), as a widespread and green solvent, already showed its excellent performance on CO₂ capture and absorption, indicating its potential application in low concentration CO₂ capture. In this review, we first summarized the current methods and strategies for direct capture from low concentration CO₂ in both the atmosphere and manned closed spaces. Then, the multi-scale simulation methods of CO₂ capture by ionic liquids are described in detail, including screening ionic liquids by COSMO-RS methods, capture mechanism by density functional theory and molecular dynamics simulation, and absorption process by computational fluid dynamics simulation. Lastly, some typical IL-based green technologies for low concentration CO₂ capture, such as functionalized ILs, co-solvent systems with ILs, and supported materials based on ILs, are introduced, and analyzed the subtle possibility in manned closed spaces. Finally, we look forward to the technology and development of low concentration CO₂ capture, which can meet the needs of human survival in closed space and proposed that supported materials with ionic liquids have great advantages and infinite possibilities in the vital area.     

重轨矫直速度对矫后残余应力的影响分析

针对矫直速度对重轨矫后残余应力的影响进行研究,利用Pro/E建立60kg·m-1重轨九辊水平矫直模型,采用ANSYS Workbench对重轨矫直过程进行有限元数值模拟,通过现场矫直规程对采用现场矫直速度以及假定矫直速度得到的重轨矫后残余应力进行分析比较,得出了在其余条件不变的情况下重轨的矫直速度在1.4~1.6m·s-1的范围内其轨底矫后纵向残余拉应力小于250MPa,且残余应力分布合理,满足矫直要求,相比于现场采用的1.2m·s-1的矫直速度其生产效率最大能够提高16.7%~33.3%。     

咖啡渣活性炭的制备、表征及其对Cr(Ⅵ)的吸附机制研究

以碘吸附值为评价指标，活化时间、活化温度和浸渍比为影响因素，采用响应面法试验设计对磷酸活化法制备咖啡渣活性炭的工艺条件进行优化，并通过静态吸附试验研究了不同吸附时间、溶液pH值和吸附温度条件下，活性炭对水溶液中Cr（Ⅵ）吸附性能的影响，最后利用Langmuir、Freundlich吸附等温方程、准一级动力学方程、准二级动力学方程和颗粒内部扩散方程进行拟合。试验结果表明，制备咖啡渣活性炭的最佳工艺条件为活化时间1 h、活化温度498℃、浸渍比1.72；在此条件下活性炭得率为30.4%，碘吸附值为（799±16）mg/g，比表面积为1 006 m²/g，孔容为0.779 cm³/g、微孔孔容为0.051 cm³/g、平均孔径为3.088 nm。较低pH值和较高温度能够促进活性炭对Cr（Ⅵ）的吸附；Langmuir等温方程能够更好地描述活性炭对Cr（Ⅵ）的吸附效果；活性炭对Cr（Ⅵ）的吸附分3个阶段：快速吸附阶段、慢速吸附阶段和吸附平衡阶段，10 min内可完成吸附总量的79%，360 min内达到吸附平衡，该吸附过程符合准二级吸附动力学方程。分析表明咖啡渣活性炭对Cr（Ⅵ）的吸附主要为单分子层的化学吸附。